The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes (Q37991179)

26 August 2017

The biology and chemistry of high-valent iron-oxo and iron-nitrido complexes (English)

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26 August 2017

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Karsten Meyer

3

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author name string

Johannes Hohenberger

series ordinal

1

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PubMed ID

22395611

26 August 2017

Kallol Ray

series ordinal

2

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PubMed ID

22395611

26 August 2017

language of work or name

English

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publication date

6 March 2012

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26 August 2017

Nature Communications

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26 August 2017

3

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26 August 2017

720

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https://scigraph.springernature.com/pub.10.1038/ncomms1718

26 August 2017

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12 December 2020

P450 enzymes: their structure, reactivity, and selectivity-modeled by QM/MM calculations

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12 December 2020

High-valent iron in chemical and biological oxidations

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12 December 2020

Self-assembly of a tetradecanuclear iron nitride cluster

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12 December 2020

Dioxygen activation in soluble methane monooxygenase

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12 December 2020

Structures of the high-valent metal-ion haem-oxygen intermediates in peroxidases, oxygenases and catalases.

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Characterization of a high-spin non-heme Fe(III)-OOH intermediate and its quantitative conversion to an Fe(IV)═O complex

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12 December 2020

Near-stoichiometric conversion of H(2)O(2) to Fe(IV)=O at a nonheme iron(II) center. Insights into the O-O bond cleavage step

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12 December 2020

Observation of Fe(V)=O using variable-temperature mass spectrometry and its enzyme-like C–H and C=C oxidation reactions

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12 December 2020

Oxidative group transfer to a triiron complex to form a nucleophilic μ(3)-nitride, [Fe3(μ(3)-N)]-.

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12 December 2020

The geometric and electronic structure of [(cyclam-acetato)Fe(N)]+: a genuine iron(v) species with a ground-state spin S = 1/2.

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12 December 2020

Aqueous FeIV==O: spectroscopic identification and oxo-group exchange

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12 December 2020

Nitrogenase MoFe-protein at 1.16 A resolution: a central ligand in the FeMo-cofactor

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12 December 2020

Fast water oxidation using iron.

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12 December 2020

The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathway

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12 December 2020

Reactivity of high-valent iron-oxo species in enzymes and synthetic reagents: a tale of many states

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12 December 2020

Catalytic C-H bond amination from high-spin iron imido complexes.

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12 December 2020

Cytochrome P450 compound I: capture, characterization, and C-H bond activation kinetics

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12 December 2020

The fundamental role of exchange-enhanced reactivity in C-H activation by S=2 oxo iron(IV) complexes

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12 December 2020

Dioxygen activation by mononuclear nonheme iron(II) complexes generates iron-oxygen intermediates in the presence of an NADH analogue and proton

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12 December 2020

The mechanism of Klebsiella pneumoniae nitrogenase action. Simulation of the dependences of H2-evolution rate on component-protein concentration and ratio and sodium dithionite concentration

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12 December 2020

Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates

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12 December 2020

On the status of ferryl protonation

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12 December 2020

Resonance Raman spectroscopy of chloroperoxidase compound II provides direct evidence for the existence of an iron(IV)-hydroxide

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12 December 2020

Spectroscopic and computational evaluation of the structure of the high-spin Fe(IV)-oxo intermediates in taurine: alpha-ketoglutarate dioxygenase from Escherichia coli and its His99Ala ligand variant.

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12 December 2020

Nonheme oxo-iron(IV) intermediates form an oxyl radical upon approaching the C-H bond activation transition state

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12 December 2020

A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity

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12 December 2020

Structure and reactivity of a mononuclear non-haem iron(III)-peroxo complex

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12 December 2020

The mystery of cytochrome P450 Compound I: a mini-review dedicated to Klaus Ruckpaul

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12 December 2020

Mid- to high-valent imido and nitrido complexes of iron

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12 December 2020

Moessbauer and electron paramagnetic resonance studies of horseradish peroxidase and its catalytic intermediates

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12 December 2020

The mechanism of Klebsiella pneumoniae nitrogenase action. Pre-steady-state kinetics of H2 formation

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12 December 2020

A synthetic precedent for the [FeIV2(mu-O)2] diamond core proposed for methane monooxygenase intermediate Q.

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12 December 2020

Evidence for two ferryl species in chloroperoxidase compound II.

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12 December 2020

Chemical and Spectroscopic Evidence for an FeV-Oxo Complex

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12 December 2020

Current challenges of modeling diiron enzyme active sites for dioxygen activation by biomimetic synthetic complexes

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12 December 2020

Electronic structure and spectroscopy of “superoxidized” iron centers in model systems: theoretical and experimental trends

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12 December 2020

Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer.

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12 December 2020

Crystallographic and Spectroscopic Characterization of a Nonheme Fe(IV)&cjs0811;O Complex

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12 December 2020

XAS characterization of a nitridoiron(IV) complex with a very short Fe-N bond

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12 December 2020

The road to non-heme oxoferryls and beyond

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12 December 2020

Peroxo and oxo intermediates in mononuclear nonheme iron enzymes and related active sites

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12 December 2020

Rapid freeze-quench 57Fe Mössbauer spectroscopy: monitoring changes of an iron-containing active site during a biochemical reaction

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12 December 2020

An Octahedral Coordination Complex of Iron(VI)

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12 December 2020

Proton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediate

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12 December 2020

Characterization of a Genuine Iron(V)−Nitrido Species by Nuclear Resonant Vibrational Spectroscopy Coupled to Density Functional Calculations

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12 December 2020

High-valent nonheme iron-oxo species in biomimetic oxidations

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12 December 2020

Structural and spectroscopic characterization of an electrophilic iron nitrido complex

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12 December 2020

Spectroscopic and quantum chemical characterization of the electronic structure and bonding in a non-heme FeIV[double bond]O complex

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12 December 2020

Formation, structure, and EPR detection of a high spin Fe(IV)-oxo species derived from either an Fe(III)-oxo or Fe(III)-OH complex.

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12 December 2020

X-ray emission spectroscopy evidences a central carbon in the nitrogenase iron-molybdenum cofactor

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12 December 2020

An Iron Nitride Complex

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12 December 2020

O2 activation by nonheme iron complexes: A monomeric Fe(III)-Oxo complex derived from O2

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12 December 2020

A thiolate-ligated nonheme oxoiron(IV) complex relevant to cytochrome P450

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12 December 2020

Non-heme Fe(IV)-oxo intermediates

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12 December 2020

electrochemical generation of a nonheme oxoiron(IV) complex

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12 December 2020

What singles out the FeO2+ moiety? A density-functional theory study of the methane-to-methanol reaction catalyzed by the first row transition-metal oxide dications MO(H2O)(p)2+, M = V-Cu

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12 December 2020

Enhanced reactivities of iron(IV)-oxo porphyrin pi-cation radicals in oxygenation reactions by electron-donating axial ligands

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12 December 2020

A tetrahedrally coordinated L3Fe-Nx platform that accommodates terminal nitride (Fe(IV)N) and dinitrogen (Fe(I)-N2-Fe(I)) ligands

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12 December 2020

Efficient water oxidation catalysts based on readily available iron coordination complexes

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12 December 2020

Dioxygen activation by a non-heme iron(II) complex: formation of an iron(IV)-oxo complex via C-H activation by a putative iron(III)-superoxo species

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12 December 2020

Mononuclear (Nitrido)iron(V) and (Oxo)iron(IV) Complexes via Photolysis of [(cyclam-acetato)FeIII(N3)]+and Ozonolysis of [(cyclam-acetato)FeIII(O3SCF3)]+in Water/Acetone Mixtures‡

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12 December 2020

Propene activation by the oxo-iron active species of taurine/alpha-ketoglutarate dioxygenase (TauD) enzyme. How does the catalysis compare to heme-enzymes?

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12 December 2020

An Fe2IVO2 Diamond Core Structure for the Key Intermediate Q of Methane Monooxygenase

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12 December 2020

Metal-metal interactions involving metalloporphyrins. III. Conversion of tetraphenylporphinatoiron(III) azide to an N-bridged hemin dimer

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12 December 2020

Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstraction

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12 December 2020

EPR spectroscopic trapping of the active species of nonheme iron-catalyzed oxidation.

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12 December 2020

Theoretical predictions of a highly reactive non-heme Fe(IV)=O complex with a high-spin ground state.

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12 December 2020

Atom transfer as a preparative tool in coordination chemistry. Synthesis and characterization of Cr(V) nitrido complexes of bidentate ligands

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12 December 2020

The mechanism of Klebsiella pneumoniae nitrogenase action. Pre-steady-state kinetics of an enzyme-bound intermediate in N2 reduction and of NH3 formation

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12 December 2020

Theoretical studies of O-O bond formation in photosystem II

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12 December 2020

Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron.

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12 December 2020

Spin Crossover in a Four-Coordinate Iron(II) Complex

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12 December 2020

O-O bond formation mediated by a hexanuclear iron complex supported on a stannoxane core.

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12 December 2020

The mechanism of Klebsiella pneumoniae nitrogenase action. The determination of rate constants required for the simulation of the kinetics of N2 reduction and H2 evolution

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12 December 2020

Evidence for basic ferryls in cytochromes P450.

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12 December 2020

Reactive intermediates in oxygenation reactions with mononuclear nonheme iron catalysts

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12 December 2020

Iron-catalyzed halogenation of alkanes: modeling of nonheme halogenases by experiment and DFT calculations

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12 December 2020

Photocatalytic generation of a non-heme oxoiron(IV) complex with water as an oxygen source

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12 December 2020

N₂reduction and hydrogenation to ammonia by a molecular iron-potassium complex

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12 December 2020

Electronic structure and reactivity of high-valent oxo iron porphyrins

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https://api.crossref.org/works/10.1038%2FNCOMMS1718

7 January 2021

Insights into the P-to-Q conversion in the catalytic cycle of methane monooxygenase from a synthetic model system.

1 reference

https://api.crossref.org/works/10.1038%2FNCOMMS1718

7 January 2021

Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage

1 reference

https://api.crossref.org/works/10.1038%2FNCOMMS1718

7 January 2021

Resonance Raman spectra of nitridoiron(V) porphyrin intermediates produced by laser photolysis

1 reference

https://api.crossref.org/works/10.1038%2FNCOMMS1718

7 January 2021

Photolysis ofcis- andtrans-[FeIII(cyclam)(N3)2]+Complexes: Spectroscopic Characterization of a Nitridoiron(V) Species

1 reference

https://api.crossref.org/works/10.1038%2FNCOMMS1718

7 January 2021

Nitridomanganese(V) and -(VI) Complexes Containing Macrocyclic Amine Ligands

1 reference

https://api.crossref.org/works/10.1038%2FNCOMMS1718

7 January 2021

Synthesis, Structure, and Reactivity of an Iron(V) Nitride

1 reference

https://api.crossref.org/works/10.1038%2FNCOMMS1718

7 January 2021

μ-Nitridodiiron Complexes with Asymmetric[FeIVN-FeIII]4+ and Symmetric[FeIVNFeIV]5+ Structural Elements

1 reference

https://api.crossref.org/works/10.1038%2FNCOMMS1718

7 January 2021

The Molecular and Electronic Structure of Symmetrically and Asymmetrically Coordinated, Non-Heme Iron Complexes Containing [FeIII(μ-N)FeIV]4+ (S=3/2) and [FeIV(μ-N)FeIV]5+ (S=0) Cores

1 reference

https://api.crossref.org/works/10.1038%2FNCOMMS1718

7 January 2021

Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution

1 reference

https://api.crossref.org/works/10.1038%2FNCOMMS1718

7 January 2021

Identifiers

DOI

10.1038/NCOMMS1718

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26 August 2017

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PubMed ID

22395611