Formation, structure, and EPR detection of a high spin Fe(IV)-oxo species derived from either an Fe(III)-oxo or Fe(III)-OH complex. (Q42424341)

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9 February 2020

title

Formation, structure, and EPR detection of a high spin Fe(IV)-oxo species derived from either an Fe(III)-oxo or Fe(III)-OH complex (English)

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9 February 2020

3

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author name string

David C Lacy

1

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9 February 2020

Rupal Gupta

2

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9 February 2020

John Greaves

4

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9 February 2020

Joseph W Ziller

5

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9 February 2020

Michael P Hendrich

6

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9 February 2020

A S Borovik

7

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language of work or name

English

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publication date

1 September 2010

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Journal of the American Chemical Society

9 February 2020

published in

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volume

132

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issue

35

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9 February 2020

page(s)

12188-12190

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The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathway

9 February 2020

cites work

1 reference

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Role of the secondary coordination sphere in metal-mediated dioxygen activation

28 May 2018

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A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity

28 May 2018

1 reference

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C-H bond cleavage with reductants: re-investigating the reactivity of monomeric Mn(III/IV)-oxo complexes and the role of oxo ligand basicity

28 May 2018

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The effects of hydrogen bonds on metal-mediated O2 activation and related processes

28 May 2018

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The road to non-heme oxoferryls and beyond

28 May 2018

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Non-heme Fe(IV)-oxo intermediates

28 May 2018

1 reference

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High-valent iron(IV)-oxo complexes of heme and non-heme ligands in oxygenation reactions

28 May 2018

1 reference

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Nature's inventory of halogenation catalysts: oxidative strategies predominate

28 May 2018

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FeII/alpha-ketoglutarate-dependent hydroxylases and related enzymes

28 May 2018

1 reference

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Geometric and electronic structure/function correlations in non-heme iron enzymes

28 May 2018

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Determination by high-frequency and -field EPR of zero-field splitting in iron(IV) oxo complexes: implications for intermediates in nonheme iron enzymes

28 May 2018

1 reference

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Spectroscopic and computational evaluation of the structure of the high-spin Fe(IV)-oxo intermediates in taurine: alpha-ketoglutarate dioxygenase from Escherichia coli and its His99Ala ligand variant.

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2942906

X-ray absorption spectroscopy and density functional theory studies of [(H3buea)FeIII-X]n- (X = S2-, O2-, OH-): comparison of bonding and hydrogen bonding in oxo and sulfido complexes

16 August 2018

1 reference

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Application of Badger's rule to heme and non-heme iron-oxygen bonds: an examination of ferryl protonation states.

16 August 2018

1 reference

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Monomeric MnIII/II and FeIII/II Complexes with Terminal Hydroxo and Oxo Ligands: Probing Reactivity via O−H Bond Dissociation Energies

16 August 2018

1 reference

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The first direct characterization of a high-valent iron intermediate in the reaction of an alpha-ketoglutarate-dependent dioxygenase: a high-spin FeIV complex in taurine/alpha-ketoglutarate dioxygenase (TauD) from Escherichia coli

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2942906

Structures of Nonheme Oxoiron(IV) Complexes from X-ray Crystallography, NMR Spectroscopy, and DFT Calculations

16 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2942906

Crystallographic and Spectroscopic Characterization of a Nonheme Fe(IV)&cjs0811;O Complex

1 December 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2942906

Aqueous FeIV==O: spectroscopic identification and oxo-group exchange

1 December 2018

1 reference

PubMed

https://pubmed.ncbi.nlm.nih.gov/20704272

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12 December 2020

based on heuristic

O2 activation by nonheme iron complexes: A monomeric Fe(III)-Oxo complex derived from O2

1 reference

PubMed

https://pubmed.ncbi.nlm.nih.gov/20704272

inferred from PubMed ID database lookup

12 December 2020

based on heuristic

Bioinspired hydrogen bond motifs in ligand design: the role of noncovalent interactions in metal ion mediated activation of dioxygen

1 reference

PubMed

https://pubmed.ncbi.nlm.nih.gov/20704272

inferred from PubMed ID database lookup

12 December 2020

based on heuristic

Identifiers

DOI

10.1021/JA1047818

1 reference

https://www.ebi.ac.uk/europepmc/webservices/rest/search?query=EXT_ID:20704272%20AND%20SRC:MED&resulttype=core&format=json

9 February 2020

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9 February 2020

PubMed publication ID

20704272

1 reference