Dioxygen activation in soluble methane monooxygenase (Q34819410)

4 August 2017

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title

Dioxygen activation in soluble methane monooxygenase (English)

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4 August 2017

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Christine E Tinberg

1

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4 August 2017

Stephen J Lippard

series ordinal

2

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4 August 2017

language of work or name

English

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publication date

10 March 2011

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Accounts of Chemical Research

4 August 2017

published in

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4 August 2017

volume

44

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4 August 2017

issue

4

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4 August 2017

page(s)

280-288

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Insights into the different dioxygen activation pathways of methane and toluene monooxygenase hydroxylases

4 August 2017

cites work

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Oxidation Reactions Performed by Soluble Methane Monooxygenase Hydroxylase Intermediates Hperoxo and Q Proceed by Distinct Mechanisms

8 July 2018

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Current challenges of modeling diiron enzyme active sites for dioxygen activation by biomimetic synthetic complexes

8 July 2018

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Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage

8 July 2018

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8 July 2018

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Carboxylate as the protonation site in (Peroxo)diiron(III) model complexes of soluble methane monooxygenase and related diiron proteins

8 July 2018

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Revisiting the mechanism of dioxygen activation in soluble methane monooxygenase from M. capsulatus (Bath): evidence for a multi-step, proton-dependent reaction pathway

8 July 2018

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Human deoxyhypusine hydroxylase, an enzyme involved in regulating cell growth, activates O2 with a nonheme diiron center

8 July 2018

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Crystallographic and catalytic studies of the peroxide-shunt reaction in a diiron hydroxylase

8 July 2018

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Iron complexes of dendrimer-appended carboxylates for activating dioxygen and oxidizing hydrocarbons

8 July 2018

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A synthetic precedent for the [FeIV2(mu-O)2] diamond core proposed for methane monooxygenase intermediate Q.

8 July 2018

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Substrate trafficking and dioxygen activation in bacterial multicomponent monooxygenases.

8 July 2018

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Intermediates in dioxygen activation by methane monooxygenase: a QM/MM study

8 July 2018

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Evidence for C-H cleavage by an iron-superoxide complex in the glycol cleavage reaction catalyzed by myo-inositol oxygenase

8 July 2018

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Stalking intermediates in oxygen activation by iron enzymes: motivation and method

8 July 2018

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8 July 2018

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Intermediates in the oxygenation of a nonheme diiron(II) complex, including the first evidence for a bound superoxo species

8 July 2018

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Synthetic models for non-heme carboxylate-bridged diiron metalloproteins: strategies and tactics.

8 July 2018

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Mechanistic studies on the hydroxylation of methane by methane monooxygenase.

8 July 2018

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Reactions of methane monooxygenase intermediate Q with derivatized methanes

8 July 2018

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8 July 2018

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Dioxygen Activation and Methane Hydroxylation by Soluble Methane Monooxygenase: A Tale of Two Irons and Three Proteins A list of abbreviations can be found in Section 7.

8 July 2018

1 reference

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Crystal structures of the soluble methane monooxygenase hydroxylase from Methylococcus capsulatus (Bath) demonstrating geometrical variability at the dinuclear iron active site

8 July 2018

1 reference

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Xenon and halogenated alkanes track putative substrate binding cavities in the soluble methane monooxygenase hydroxylase

8 July 2018

1 reference

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Oxygen kinetic isotope effects in soluble methane monooxygenase

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3079780

Oxygen activation catalyzed by methane monooxygenase hydroxylase component: proton delivery during the O-O bond cleavage steps.

8 July 2018

1 reference

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Direct spectroscopic and kinetic evidence for the involvement of a peroxodiferric intermediate during the ferroxidase reaction in fast ferritin mineralization

8 July 2018

1 reference

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Crystal structure of a bacterial non-haem iron hydroxylase that catalyses the biological oxidation of methane

8 July 2018

1 reference

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Structural model studies for the peroxo intermediate P and the reaction pathway from P-->Q of methane monooxygenase using broken-symmetry density functional calculations

8 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3079780

Unraveling the reactive species of a functional non-heme iron monooxygenase model using stopped-flow UV-vis spectroscopy

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3079780

Reactions of the peroxo intermediate of soluble methane monooxygenase hydroxylase with ethers

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3079780

Nature of the peroxo intermediate of the W48F/D84E ribonucleotide reductase variant: implications for O2 activation by binuclear non-heme iron enzymes

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3079780

Dioxygen activation in methane monooxygenase: a theoretical study

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3079780

Mössbauer studies of the formation and reactivity of a quasi-stable peroxo intermediate of stearoyl-acyl carrier protein Delta 9-desaturase

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3079780

The Ferroxidase Reaction of Ferritin Reveals a Diferric μ-1,2 Bridging Peroxide Intermediate in Common with Other O2-Activating Non-Heme Diiron Proteins†

26 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=3079780

Kinetics and Activation Thermodynamics of Methane Monooxygenase CompoundQFormation and Reaction with Substrates†

9 December 2018

1 reference

12 December 2020

Dioxygen Activation by Enzymes Containing Binuclear Non-Heme Iron Clusters

1 reference

12 December 2020

Transient intermediates of the methane monooxygenase catalytic cycle

1 reference

12 December 2020

Peroxodiferric intermediate of stearoyl-acyl carrier protein delta 9 desaturase: oxidase reactivity during single turnover and implications for the mechanism of desaturation

1 reference

12 December 2020

O2 activation by non-heme diiron proteins: identification of a symmetric mu-1,2-peroxide in a mutant of ribonucleotide reductase

1 reference

12 December 2020

O-O bond cleavage and alkane hydroxylation in methane monooxygenase

1 reference

12 December 2020

Peroxo-type intermediates in class I ribonucleotide reductase and related binuclear non-heme iron enzymes

1 reference

12 December 2020

Structural and spectroscopic characterization of (mu-hydroxo or mu-oxo)(mu-peroxo)diiron(III) complexes: models for peroxo intermediates of non-heme diiron proteins

1 reference

12 December 2020

An Fe2IVO2 Diamond Core Structure for the Key Intermediate Q of Methane Monooxygenase

1 reference

12 December 2020

Identifiers

DOI

10.1021/AR1001473

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4 August 2017

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4 August 2017

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