Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage (Q40185445)

18 September 2017

Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage (English)

1 reference

18 September 2017

Genqiang Xue

1

1 reference

18 September 2017

Raymond De Hont

series ordinal

2

1 reference

18 September 2017

Eckard Münck

series ordinal

3

1 reference

18 September 2017

Lawrence Que

series ordinal

4

1 reference

18 September 2017

21 March 2010

1 reference

18 September 2017

1 reference

18 September 2017

2

1 reference

18 September 2017

5

1 reference

18 September 2017

400-405

1 reference

https://scigraph.springernature.com/pub.10.1038/nchem.586

18 September 2017

0 references

cites work

A diiron(IV) complex that cleaves strong C-H and O-H bonds

1 reference

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Observed enhancement of the reactivity of a biomimetic diiron complex by the addition of water - mechanistic insights from theoretical modeling

22 September 2017

1 reference

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A highly reactive p450 model compound I.

22 September 2017

1 reference

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A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity

22 September 2017

1 reference

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Structural analysis of the Mn(IV)/Fe(III) cofactor of Chlamydia trachomatis ribonucleotide reductase by extended X-ray absorption fine structure spectroscopy and density functional theory calculations

22 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2859466

A synthetic precedent for the [FeIV2(mu-O)2] diamond core proposed for methane monooxygenase intermediate Q.

22 September 2017

1 reference

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Spectroscopic and quantum chemical studies on low-spin FeIV=O complexes: Fe-O bonding and its contributions to reactivity

22 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2859466

The road to non-heme oxoferryls and beyond

22 September 2017

1 reference

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Non-heme Fe(IV)-oxo intermediates

22 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2859466

Reactivity of high-valent iron-oxo species in enzymes and synthetic reagents: a tale of many states

22 September 2017

1 reference

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Intermediates in dioxygen activation by methane monooxygenase: a QM/MM study

22 September 2017

1 reference

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High-valent nonheme iron-oxo species in biomimetic oxidations

22 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2859466

Stalking intermediates in oxygen activation by iron enzymes: motivation and method

22 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2859466

Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates

22 September 2017

1 reference

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Mechanistic studies on the hydroxylation of methane by methane monooxygenase.

22 September 2017

1 reference

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Heme-Containing Oxygenases

22 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2859466

Geometric and electronic structure/function correlations in non-heme iron enzymes

22 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2859466

Understanding C-H bond oxidations: H. and H- transfer in the oxidation of toluene by permanganate

22 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2859466

C-H bond cleavage with reductants: re-investigating the reactivity of monomeric Mn(III/IV)-oxo complexes and the role of oxo ligand basicity

22 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2859466

Mössbauer and DFT study of the ferromagnetically coupled diiron(IV) precursor to a complex with an Fe(IV)(2)O(2) diamond core

15 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2859466

Oxidative reactivity difference among the metal oxo and metal hydroxo moieties: pH dependent hydrogen abstraction by a manganese(IV) complex having two hydroxide ligands

20 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2859466

Monomeric MnIII/II and FeIII/II Complexes with Terminal Hydroxo and Oxo Ligands: Probing Reactivity via O−H Bond Dissociation Energies

20 August 2018

1 reference

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Two-state reactivity in alkane hydroxylation by non-heme iron-oxo complexes

20 August 2018

1 reference

12 December 2020

Theoretical Model Studies of the Iron Dimer Complex of MMO and RNR

1 reference

12 December 2020

Aqueous FeIV==O: spectroscopic identification and oxo-group exchange

1 reference

12 December 2020

Dioxygen Activation by Enzymes Containing Binuclear Non-Heme Iron Clusters

1 reference

12 December 2020

Direct evidence for an iron(IV)-oxo porphyrin pi-cation radical as an active oxidant in catalytic oxygenation reactions

1 reference

12 December 2020

Theoretical investigation of C--H hydroxylation by (N4Py)Fe(IV)=O(2+): an oxidant more powerful than P450?

1 reference

12 December 2020

What singles out the FeO2+ moiety? A density-functional theory study of the methane-to-methanol reaction catalyzed by the first row transition-metal oxide dications MO(H2O)(p)2+, M = V-Cu

1 reference

12 December 2020

Selective oxidation of aliphatic C-H bonds in the synthesis of complex molecules

1 reference

12 December 2020

An Fe2IVO2 Diamond Core Structure for the Key Intermediate Q of Methane Monooxygenase

1 reference

12 December 2020

Electronic structure and reactivity of high-valent oxo iron porphyrins

1 reference

Crossref

https://api.crossref.org/works/10.1038%2FNCHEM.586

7 January 2021

inferred from DOI database lookup

Insights into the P-to-Q conversion in the catalytic cycle of methane monooxygenase from a synthetic model system.

1 reference

Crossref

https://api.crossref.org/works/10.1038%2FNCHEM.586

7 January 2021

inferred from DOI database lookup

Identifiers

DOI

10.1038/NCHEM.586

1 reference

18 September 2017

1 reference

18 September 2017

1 reference