Not a simple redirect: you could say an anchored redirect.
The problem doesn't really lie here, because the URL constructed with the identifier is fine for anyone with ODNB access. It lies with the ODNB index pages, which hide what is happening.
http://www.oxforddnb.com/public/hub/489.html does make it clear that there are two people. With some more work, they could do more.
At present, one can use http://oxfordindex.oup.com/. The search
http://oxfordindex.oup.com/search?q=Edward+Rudge
shows there are two "Edward Rudge" pages. It also gives the opening
"Rudge, Edward (1763-1846), botanist and antiquary, was born in Evesham on 27 June 1763, the son of Edward Rudge ..."
of one. Following the link one gets to
http://oxfordindex.oup.com/view/10.1093/ref:odnb/24250?rskey=VMOg7k&result=3
which shows the (unpadded) OBIN as 24250
So at present where there are two identifiers, it is possible to see which is for the main topic, at least.
~~~~