Thermodynamic control of asymmetric amplification in amino acid catalysis. (Q47843872)

6 February 2018

title

Thermodynamic control of asymmetric amplification in amino acid catalysis. (English)

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6 February 2018

author

Martin Klussmann

1

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6 February 2018

author name string

Hiroshi Iwamura

2

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Suju P Mathew

3

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David H Wells

4

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Urvish Pandya

5

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6 February 2018

Alan Armstrong

6

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Donna G Blackmond

7

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language of work or name

English

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publication date

1 June 2006

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6 February 2018

published in

Nature

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6 February 2018

volume

441

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6 February 2018

page(s)

621-623

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issue

7093

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6 February 2018

https://scigraph.springernature.com/pub.10.1038/nature04780

exact match

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cites work

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Origins of asymmetric amplification in autocatalytic alkylzinc additions.

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Kinetic evidence for a tetrameric transition state in the asymmetric autocatalytic alkylation of pyrimidyl aldehydes.

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Solution structure and reagent binding of the zinc alkoxide catalyst in the Soai asymmetric autocatalytic reaction.

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Amplification of enantiomeric excess in a proline-mediated reaction

21 January 2018

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In situ catalyst improvement in the proline-mediated alpha-amination of aldehydes

21 January 2018

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Kinetic and Stereochemical Evidence for the Involvement of Only One Proline Molecule in the Transition States of Proline-Catalyzed Intra- and Intermolecular Aldol Reactions

21 January 2018

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Kinetic aspects of nonlinear effects in asymmetric catalysis

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Origin of organic molecules and biomolecular homochirality

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Acyclic amino acid-catalyzed direct asymmetric aldol reactions: alanine, the simplest stereoselective organocatalyst.

21 January 2018

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Exploratory studies to investigate a linked prebiotic origin of RNA and coded peptides

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Serine octamer reactions: indicators of prebiotic relevance

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A mechanism for the amplification of fluctuations in racemic mixtures

21 January 2018

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Chiral autocatalysis, spontaneous symmetry breaking, and stochastic behavior

21 January 2018

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Chiral symmetry breaking in sodium chlorate crystallizaton

21 January 2018

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Formation of highly enantioenriched microenvironments by stochastic sorting of conglomerate crystals: A plausible mechanism for generation of enantioenrichment on the prebiotic earth

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Asymmetric autocatalysis and amplification of enantiomeric excess of a chiral molecule

21 January 2018

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Nonlinear Effects in Asymmetric Synthesis and Stereoselective Reactions: Ten Years of Investigation

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7 January 2021

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Identifiers

DOI

10.1038/NATURE04780

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6 February 2018

Dimensions Publication ID

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6 February 2018