Gram-Scale Synthesis of Chiral Cyclopropane-Containing Drugs and Drug Precursors with Engineered Myoglobin Catalysts Featuring Complementary Stereoselectivity. (Q47099176)

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scientific article published on 25 November 2016

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English	Gram-Scale Synthesis of Chiral Cyclopropane-Containing Drugs and Drug Precursors with Engineered Myoglobin Catalysts Featuring Complementary Stereoselectivity.	scientific article published on 25 November 2016

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scholarly article

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28 March 2020

Gram-Scale Synthesis of Chiral Cyclopropane-Containing Drugs and Drug Precursors with Engineered Myoglobin Catalysts Featuring Complementary Stereoselectivity (English)

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28 March 2020

stereoselectivity

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based on heuristic

inferred from title

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based on heuristic

inferred from title

4

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1

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author name string

Gopeekrishnan Sreenilayam

2

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28 March 2020

Vikas Tyagi

3

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publication date

25 November 2016

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Angewandte Chemie International Edition

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16110-16114

1 reference

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28 March 2020

The "Cyclopropyl Fragment" is a Versatile Player that Frequently Appears in Preclinical/Clinical Drug Molecules

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Efficient conversion of primary azides to aldehydes catalyzed by active site variants of myoglobin

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Myoglobin-Catalyzed Olefination of Aldehydes

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Mutating a Highly Conserved Residue in Diverse Cytochrome P450s Facilitates Diastereoselective Olefin Cyclopropanation

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Intermolecular carbene S-H insertion catalysed by engineered myoglobin-based catalysts†.

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Guidelines for development and implementation of biocatalytic P450 processes

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Highly diastereoselective and enantioselective olefin cyclopropanation using engineered myoglobin-based catalysts

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A serine-substituted P450 catalyzes highly efficient carbene transfer to olefins in vivo

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Olefin Cyclopropanation via Carbene Transfer Catalyzed by Engineered Cytochrome P450 Enzymes

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Stereoselective cyclopropanation reactions

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Recent developments in asymmetric cyclopropanation

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Using mutability landscapes of a promiscuous tautomerase to guide the engineering of enantioselective Michaelases

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Improved Cyclopropanation Activity of Histidine-Ligated Cytochrome P450 Enables the Enantioselective Formal Synthesis of Levomilnacipran

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Identifiers

10.1002/ANIE.201608680

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28 March 2020

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28 March 2020

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