Gold(I)-catalyzed enantioselective polycyclization reactions (Q41203677)

28 September 2017

Gold(I)-catalyzed enantioselective polycyclization reactions (English)

1 reference

28 September 2017

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3

F Dean Toste

1 reference

28 September 2017

Steven G Sethofer

1

1 reference

PMCID

2888676

28 September 2017

Timo Mayer

series ordinal

2

1 reference

PMCID

2888676

28 September 2017

language of work or name

English

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publication date

1 June 2010

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Journal of the American Chemical Society

28 September 2017

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28 September 2017

132

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28 September 2017

24

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28 September 2017

8276-8277

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Enantioselective thiourea-catalyzed cationic polycyclizations

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Enantioselective polyene cyclization via organo-SOMO catalysis

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Asymmetric oxidative cation/olefin cyclization of polyenes: evidence for reversible cascade cyclization

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Gold-catalyzed cycloisomerizations of enynes: a mechanistic perspective

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Cycloisomerization of 1,n-enynes: challenging metal-catalyzed rearrangements and mechanistic insights.

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Reversibility effects on the stereoselectivity of Pt(II)-mediated cascade poly-ene cyclizations

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Catalytic carbophilic activation: catalysis by platinum and gold pi acids

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

The mechanistic puzzle of transition-metal-catalyzed skeletal rearrangements of enynes

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

A case study in biomimetic total synthesis: polyolefin carbocyclizations to terpenes and steroids

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Intermolecular hydroamination of ethylene and 1-alkenes with cyclic ureas catalyzed by achiral and chiral gold(I) complexes

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

A bonding model for gold(I) carbene complexes.

28 September 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Gold(I)-catalyzed stereoselective olefin cyclopropanation.

17 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Asymmetric Au(i)-catalyzed synthesis of bicyclo[4.1.0]heptene derivatives via a cycloisomerization process of 1,6-enynes

17 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Gold(I)-catalyzed enantioselective synthesis of benzopyrans via rearrangement of allylic oxonium intermediates

19 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Au(I)-catalyzed ring expanding cycloisomerizations: total synthesis of ventricosene

19 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Bioinspired polyene cyclization promoted by intermolecular chiral acetal-SnCl4 or chiral N-acetal-TiCl4: investigation of the mechanism and identification of the key intermediates

19 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Gold(I)-catalyzed [2 + 2]-cycloaddition of allenenes

19 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Enantioselective halocyclization of polyprenoids induced by nucleophilic phosphoramidites.

19 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Gold-catalyzed assembly of heterobicyclic systems.

19 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Enzyme Mechanisms for Polycyclic Triterpene Formation

19 August 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

Biomimetic polyene cyclizations

4 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2888676

On the nature of the reactive intermediates in gold-catalyzed cycloisomerization reactions

2 December 2018

1 reference

12 December 2020

Gold(I)-catalyzed stereoselective formation of functionalized 2,5-dihydrofurans

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12 December 2020

Mimicking polyolefin carbocyclization reactions: gold-catalyzed intramolecular phenoxycyclization of 1,5-enynes

1 reference

12 December 2020

Mercuric triflate-catalyzed tandem cyclization leading to polycarbocycles

1 reference

12 December 2020

Pd(II)- and Pt(II)-mediated polycyclization reactions of 1,5- and 1,6-dienes: evidence in support of carbocation intermediates

1 reference

12 December 2020

Asymmetric gold-catalyzed hydroarylation/cyclization reactions

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12 December 2020

Catalyzed tandem reaction of 3-silyloxy-1,5-enynes consisting of cyclization and pinacol rearrangement

1 reference

12 December 2020

Regioselective oxidative cation-olefin cyclization of poly-enes: catalyst turnover via hydride abstraction

1 reference

12 December 2020

Gold(I)-catalyzed formation of 4-alkylidene-1,3-dioxolan-2-ones from propargylic tert-butyl carbonates

1 reference

12 December 2020

Gold(I)-catalyzed intramolecular enantioselective hydroalkoxylation of allenes

1 reference

12 December 2020

Identifiers

DOI

10.1021/JA103544P

1 reference

28 September 2017

1 reference

28 September 2017

1 reference

PMCID

2888676