On the mechanism of palladium-catalyzed aromatic C-H oxidation (Q34140301)

31 July 2017

On the mechanism of palladium-catalyzed aromatic C-H oxidation (English)

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31 July 2017

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David C Powers

1

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31 July 2017

Daphne Y Xiao

series ordinal

2

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31 July 2017

Matthias A L Geibel

series ordinal

3

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31 July 2017

Tobias Ritter

series ordinal

4

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31 July 2017

language of work or name

English

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publication date

1 October 2010

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Journal of the American Chemical Society

31 July 2017

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31 July 2017

132

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31 July 2017

14530-14536

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31 July 2017

41

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Mechanism of C-F reductive elimination from palladium(IV) fluorides

31 July 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Organopalladium(IV) chemistry

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Palladium-Catalyzed Ligand-Directed C−H Functionalization Reactions

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Mechanistic comparison between Pd-catalyzed ligand-directed C-H chlorination and C-H acetoxylation

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Synthetic and mechanistic studies of Pd-catalyzed C-H arylation with diaryliodonium salts: evidence for a bimetallic high oxidation state Pd intermediate

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Palladium(II)-catalyzed ortho alkylation of benzoic acids with alkyl halides

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Palladium- and copper-catalyzed arylation of carbon-hydrogen bonds

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Versatile Pd(OTf)2 x 2 H2O-catalyzed ortho-fluorination using NMP as a promoter

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Insights into directing group ability in palladium-catalyzed C-H bond functionalization

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Reactions of hypervalent iodine reagents with palladium: mechanisms and applications in organic synthesis

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Sigma-chelation-directed C-H functionalizations using Pd(II) and Cu(II) catalysts: regioselectivity, stereoselectivity and catalytic turnover

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Aryl-aryl bond formation by transition-metal-catalyzed direct arylation.

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Pd(II)-catalyzed ortho-trifluoromethylation of arenes using TFA as a promoter

5 July 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Bimetallic palladium catalysis: direct observation of Pd(III)-Pd(III) intermediates

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Chelating N-Heterocyclic Carbene Alkoxide as a Supporting Ligand for PdII/IVC−H Bond Functionalization Catalysis

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Palladium-catalyzed amidation of unactivated C(sp(3))-H bonds: from anilines to indolines

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Palladium-catalyzed aromatic C-H halogenation with hydrogen halides by means of electrochemical oxidation.

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Pd(II)-catalyzed amination of C-H bonds using single-electron or two-electron oxidants.

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Pd(II)/Pd(IV) catalytic enantioselective synthesis of bicyclo[3.1.0]hexanes via oxidative cyclization of enynes.

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Oxidative Pd(II)-catalyzed C-H bond amination to carbazole at ambient temperature

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Catalytic aerobic oxidation of substituted 8-methylquinolines in Pd(II)-2,6-pyridinedicarboxylic acid systems

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Direct ortho-acetoxylation of anilides via palladium-catalyzed sp(2) C-H bond oxidative activation

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Direct synthesis of bicyclic guanidines through unprecedented palladium(ii) catalysed diamination with copper chloride as oxidant.

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Palladium-catalyzed direct arylation of (hetero)arenes with aryl boronic acids

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Reactivity of Pd(II) complexes with electrophilic chlorinating reagents: isolation of Pd(IV) products and observation of C-Cl bond-forming reductive elimination

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Ortho arylation of acetanilides via Pd(II)-catalyzed C-H functionalization.

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Unprecedented formation of an acetamidate-bridged dinuclear platinum(II) terpyridyl complex-correlation of luminescence properties with the crystal forms and dimerization studies in solution.

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Intermolecular Amidation of Unactivated sp2and sp3C−H Bonds via Palladium-Catalyzed Cascade C−H Activation/Nitrene Insertion

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Highly selective C-H functionalization/halogenation of acetanilide.

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Highly regioselective Pd-catalyzed intermolecular aminoacetoxylation of alkenes and evidence for cis-aminopalladation and S(N)2 C-O bond formation.

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Unusually stable palladium(IV) complexes: detailed mechanistic investigation of C-O bond-forming reductive elimination

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Mono- and binuclear cyclometallated palladium(II) complexes containing bridging (N,O-) and terminal (N-) imidate ligands: air stable, thermally robust and recyclable catalysts for cross-coupling processes

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Palladium-catalyzed oxygenation of unactivated sp3 C-H bonds

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

A highly selective catalytic method for the oxidative functionalization of C-H bonds

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C2N2O2−Ligated Palladium(IV) Complexes

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Construction of Tetrahydrofurans by PdII/PdIV-Catalyzed Aminooxygenation of Alkenes

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Synthesis of Cyclopropanes via Pd(II/IV)-Catalyzed Reactions of Enynes

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Highly Regioselective Catalytic Oxidative Coupling Reactions: Synthetic and Mechanistic Investigations

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

A Simple Catalytic Method for the Regioselective Halogenation of Arenes

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Oxone as an Inexpensive, Safe, and Environmentally Benign Oxidant for C−H Bond Oxygenation

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

Palladium-Catalyzed Fluorination of Carbon−Hydrogen Bonds

28 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2958923

High-oxidation-state palladium catalysis: new reactivity for organic synthesis

9 December 2018

1 reference

12 December 2020

Palladium-catalyzed oxidative cyclization of enynes with hydrogen peroxide as the oxidant

1 reference

12 December 2020

Emergence of palladium(IV) chemistry in synthesis and catalysis

1 reference

12 December 2020

Anilide ortho-arylation by using C-H activation methodology

1 reference

12 December 2020

Palladium-catalyzed ring-forming aminoacetoxylation of alkenes

1 reference

12 December 2020

Sequential intermolecular aminopalladation/ortho-arene C-H activation reactions of N-phenylpropiolamides with phthalimide

1 reference

12 December 2020

Palladium-catalyzed diacetoxylation of alkenes with molecular oxygen as sole oxidant

1 reference

12 December 2020

Multiple C-H activations to construct biologically active molecules in a process completely free of organohalogen and organometallic components

1 reference

12 December 2020

Palladium-catalyzed C-H bond functionalization with arylsulfonyl chlorides

1 reference

12 December 2020

Pd-catalyzed oxidative coupling with organometallic reagents via C-H activation

1 reference

12 December 2020

Advancing palladium-catalyzed C-N bond formation: bisindoline construction from successive amide transfer to internal alkenes

1 reference

12 December 2020

Synthesis of (2-oxoindolin-3-ylidene)methyl acetates involving a C-H functionalization process

1 reference

12 December 2020

Palladium-catalyzed olefin dioxygenation

1 reference

12 December 2020

Palladium-catalyzed decarboxylative arylation of C-H bonds by aryl acylperoxides

1 reference

12 December 2020

Bimetallic Pd(III) complexes in palladium-catalysed carbon–heteroatom bond formation

1 reference

12 December 2020

Suzuki-Miyaura coupling reaction by PdII-catalyzed aromatic C-H bond activation directed by an N-alkyl acetamino group

1 reference

12 December 2020

Aryl transfer between Pd(II) centers or Pd(IV) intermediates in Pd-catalyzed domino reactions

1 reference

12 December 2020

A palladium-catalyzed cyclization-oxidation sequence: synthesis of bicyclo[3.1.0]hexanes and evidence for S(N)2 C-O bond formation

1 reference

12 December 2020

Oxidative diamination of alkenes with ureas as nitrogen sources: mechanistic pathways in the presence of a high oxidation state palladium catalyst

1 reference

12 December 2020

Carbon-fluorine reductive elimination from a high-valent palladium fluoride

1 reference

12 December 2020

Pd(II)-catalyzed monoselective ortho halogenation of C-H bonds assisted by counter cations: a complementary method to directed ortho lithiation

1 reference

12 December 2020

Identifiers

DOI

10.1021/JA1054274

1 reference

31 July 2017

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31 July 2017

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