Auxiliary-assisted palladium-catalyzed arylation and alkylation of sp2 and sp3 carbon-hydrogen bonds (Q33737426)

29 July 2017

Auxiliary-assisted palladium-catalyzed arylation and alkylation of sp2 and sp3 carbon-hydrogen bonds (English)

1 reference

29 July 2017

1 reference

Dmitry Shabashov

1

1 reference

PubMed ID

20175511

29 July 2017

Olafs Daugulis

series ordinal

2

1 reference

PubMed ID

20175511

29 July 2017

language of work or name

English

0 references

publication date

1 March 2010

1 reference

Journal of the American Chemical Society

29 July 2017

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29 July 2017

132

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29 July 2017

11

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29 July 2017

3965-3972

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Total synthesis of celogentin C by stereoselective C-H activation.

29 July 2017

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Synthetic and mechanistic studies of Pd-catalyzed C-H arylation with diaryliodonium salts: evidence for a bimetallic high oxidation state Pd intermediate

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Palladium(II)-catalyzed ortho alkylation of benzoic acids with alkyl halides

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Pd(0)/PR3-catalyzed intermolecular arylation of sp3 C-H bonds

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Palladium(II)-catalyzed C-H activation/C-C cross-coupling reactions: versatility and practicality

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Palladium- and copper-catalyzed arylation of carbon-hydrogen bonds

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Pd(II)-catalyzed olefination of electron-deficient arenes using 2,6-dialkylpyridine ligands

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Application of Daugulis copper-catalyzed direct arylation to the synthesis of 5-aryl benzotriazepines

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

A general method for copper-catalyzed arylation of arene C-H bonds

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Insights into directing group ability in palladium-catalyzed C-H bond functionalization

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Direct transition metal-catalyzed functionalization of heteroaromatic compounds

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Aryl-aryl bond formation by transition-metal-catalyzed direct arylation.

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Palladium-catalyzed benzene arylation: incorporation of catalytic pivalic acid as a proton shuttle and a key element in catalyst design

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Direct Palladium-CatalyzedOrtho-Arylation of Benzylamines

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Catalysts for Suzuki-Miyaura coupling processes: scope and studies of the effect of ligand structure

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Palladium-catalyzed arylation and heteroarylation of indolizines

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Bimetallic palladium catalysis: direct observation of Pd(III)-Pd(III) intermediates

21 June 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Ruthenium-catalyzed regioselective direct alkylation of arenes with unactivated alkyl halides through C-H bond cleavage.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Cationic Ir(I)-Catalyzed sp(3) C-H Bond Alkenylation of Amides with Alkynes.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

A meta-selective copper-catalyzed C-H bond arylation

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Establishment of broadly applicable reaction conditions for the palladium-catalyzed direct arylation of heteroatom-containing aromatic compounds

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Synthesis of benzocyclobutenes by palladium-catalyzed C-H activation of methyl groups: method and mechanistic study

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Pd(II)-catalyzed cross-coupling of sp3 C-H Bonds with sp2 and sp3 boronic acids using air as the oxidant

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Two methods for direct ortho-arylation of benzoic acids.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

C-C bond formation via double C-H functionalization: aerobic oxidative coupling as a method for synthesizing heterocoupled biaryls

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Annulative tandem reactions based on Pd0/tBu3P-catalyzed cross-coupling and C(sp3)-H bond activation

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Palladium-catalyzed alkylation of aryl C-H bonds with sp3 organotin reagents using benzoquinone as a crucial promoter

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Highly regioselective arylation of sp3 C-H bonds catalyzed by palladium acetate

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

On the nature of carbon-hydrogen bond activation at rhodium and related reactions

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Regioselective synthesis of 1,5-diaryl-1H-imidazoles by palladium-catalyzed direct arylation of 1-aryl-1H-imidazoles.

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Cross-coupling of sp(3) C-H bonds and alkenes: catalytic cyclization of alkene-amide substrates

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

A ruthenium-catalyzed reaction of aromatic ketones with arylboronates: a new method for the arylation of aromatic compounds via C-H bond cleavage

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Detailed Study of C−O and C−C Bond-Forming Reductive Elimination from Stable C2N2O2−Ligated Palladium(IV) Complexes

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Palladium-Catalyzed sp3CH Activation of Simple Alkyl Groups: Direct Preparation of Indoline Derivatives fromN-Alkyl-2-bromoanilines

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Pd-Catalyzed Alkyl to Aryl Migration and Cyclization: An Efficient Synthesis of Fused Polycycles via Multiple C−H Activation

30 October 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2841226

Synthesis of 3,4-dihydroisoquinolines by a C(sp3)-H activation/electrocyclization strategy: total synthesis of coralydine

10 December 2018

1 reference

12 December 2020

Palladium-catalyzed C-H functionalization of pyridine N-oxides: highly selective alkenylation and direct arylation with unactivated arenes

1 reference

12 December 2020

Palladium-catalyzed direct arylation of simple arenes in synthesis of biaryl molecules

1 reference

12 December 2020

Aromatic ortho-benzylation reveals an unexpected reductant

1 reference

12 December 2020

High-yielding palladium-catalyzed intramolecular alkane arylation: reaction development and mechanistic studies

1 reference

12 December 2020

Novel acetoxylation and C-C coupling reactions at unactivated positions in alpha-amino acid derivatives

1 reference

12 December 2020

The Catalytic Intermolecular Orthoarylation of Phenols

1 reference

12 December 2020

Palladium-catalyzed alkylation of sp2 and sp3 C-H bonds with methylboroxine and alkylboronic acids: two distinct C-H activation pathways

1 reference

12 December 2020

Palladium-catalyzed arylation of electron-rich heterocycles with aryl chlorides

1 reference

12 December 2020

Palladium-catalyzed benzylation of heterocyclic aromatic compounds

1 reference

12 December 2020

Direct arylation of oxazoles at C2. A concise approach to consecutively linked oxazoles

1 reference

12 December 2020

Nickel-catalyzed biaryl coupling of heteroarenes and aryl halides/triflates

1 reference

12 December 2020

Ortho-arylation of benzamides

1 reference

12 December 2020

Palladium-catalyzed aryl C-H bonds activation/acetoxylation utilizing a bidentate system

1 reference

12 December 2020

Site-selective sp2 and benzylic sp3 palladium-catalyzed direct arylation

1 reference

12 December 2020

Palladium-catalyzed direct arylation of nitro-substituted aromatics with aryl halides

1 reference

12 December 2020

Suzuki-Miyaura coupling reaction by PdII-catalyzed aromatic C-H bond activation directed by an N-alkyl acetamino group

1 reference

12 December 2020

Nickel-catalyzed direct arylation of azoles with aryl bromides

1 reference

12 December 2020

Palladium-Catalyzed Methylation and Arylation of sp2and sp3C−H Bonds in Simple Carboxylic Acids

1 reference

12 December 2020

Catalytic coupling of C-H and C-I bonds using pyridine as a directing group

1 reference

12 December 2020

Chemoselective benzylic C-H activations for the preparation of condensed N-heterocycles

1 reference

12 December 2020

Identifiers

DOI

10.1021/JA910900P

1 reference

29 July 2017

1 reference

29 July 2017

1 reference

PubMed ID

20175511