Samarium diiodide mediated reactions in total synthesis (Q24645963)

Angewandte Chemie International Edition

Europe PubMed Central

title

Samarium diiodide mediated reactions in total synthesis (English)

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K C Nicolaou

1

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Shelby P Ellery

series ordinal

2

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Jason S Chen

series ordinal

3

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language of work or name

English

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publication date

2009

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published in

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volume

48

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issue

39

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page(s)

7140-65

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cites work

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Cyclization and Ring-Expansion Processes Involving Samarium Diiodide Promoted Reductive Formation and Subsequent Oxidative Ring Opening of Cyclopropanol Derivatives

7 April 2017

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Total synthesis of brevetoxin-B

7 April 2017

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Chemistry and biology of diazonamide A: second total synthesis and biological investigations

7 April 2017

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Synthesis of the monomeric unit of the lomaiviticin aglycon

7 April 2017

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Total synthesis of the originally assigned structure of vannusal B.

27 September 2017

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Total synthesis of (-)-kendomycin

27 September 2017

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Synthesis of (+)-cortistatin A.

27 September 2017

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Total synthesis of (+)-acutiphycin

27 September 2017

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Total synthesis of kinamycins C, F, and J.

27 September 2017

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What's new in stable radical chemistry?

27 September 2017

1 reference

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Total synthesis of the cytostatic marine natural product dibromophakellstatin via three-component imidazolidinone anellation

27 September 2017

1 reference

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Highly convergent total synthesis of (+)-acutiphycin

27 September 2017

1 reference

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Cascade reactions in total synthesis

27 September 2017

1 reference

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Chemistry and biology of diazonamide A: first total synthesis and confirmation of the true structure

27 September 2017

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Samarium(II)-iodide-mediated cyclizations in natural product synthesis

27 September 2017

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The first synthetic studies on pestalotiopsin A. A stereocontrolled approach to the functionalised bicyclic core

27 September 2017

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The Second Total Synthesis of Diazonamide A

27 September 2017

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Total synthesis of diazonamide A.

27 September 2017

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Sequencing Reactions with Samarium(II) Iodide

27 September 2017

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Fluorescence from Samarium(II) Iodide and Its Electron Transfer Quenching: Dynamics of the Reaction of Benzyl Radicals with Sm(II).

27 September 2017

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Total synthesis, structure revision, and absolute configuration of (-)-brevenal

27 September 2017

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Total synthesis of (-)-gambierol

30 May 2018

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Inter- and intramolecular reductive coupling reactions: an approach to the phorbol skeleton

30 May 2018

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https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Samarium diiodide-induced reductive cross-coupling of nitrones with aldehydes and ketones

30 May 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Synthesis of fused piperidinones through a radical-ionic cascade.

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Total synthesis of an anti-Helicobacter pylori agent, actinopyrone A.

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Total synthesis of (-)-martinellic acid via radical addition-cyclization-elimination reaction.

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Total synthesis of (-)-brevenal: a concise synthetic entry to the pentacyclic polyether core.

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Evolution of a synthetic strategy: total synthesis of (+/-)-welwitindolinone A isonitrile

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Biomimetic total synthesis of (-)-erinacine E.

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Synthesis and structural revision of (+/-)-laurentristich-4-ol.

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Total synthesis of the proposed structure of brevenal.

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Total synthesis of (+/-)-welwitindolinone a isonitrile

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Synthesis of a hydroxyethylene isostere of the tripeptide Arg-Gly-Leu via a convergent acyl-like radical addition strategy

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Can decarbonylation of acyl radicals be overcome in radical addition reactions? En route to a solution employing N-acyl oxazolidinones and SmI2/H2O.

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Total synthesis of (+)-hyacinthacine A2 based on SmI2-induced nitrone umpolung

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Synthetic studies on cyathins: enantioselective total synthesis of (+)-allocyathin B2.

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Studies toward diazonamide A: development of a hetero-pinacol macrocyclization cascade for the construction of the bis-macrocyclic framework of the originally proposed structure

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Radical and palladium-catalyzed cyclizations to cyclobutenes: an entry to the BCD ring system of penitrem D.

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Strained heterocycles in radical chemistry.

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

SmI2 reduced thioesters as synthons of unstable acyl radicals: direct synthesis of potential protease inhibitors via intermolecular radical addition

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Stereoselective syntheses of epothilones A and B via nitrile oxide cycloadditions and related studies

28 November 2018

1 reference

https://eutils.ncbi.nlm.nih.gov/entrez/eutils/elink.fcgi?dbfrom=pmc&linkname=pmc_refs_pubmed&retmode=json&id=2771673

Actinopyrones A, B and C, new physiologically active substances. I. Producing organism, fermentation, isolation and biological properties

28 November 2018

1 reference

12 December 2020

A catalytic asymmetric three-component 1,4-addition/aldol reaction: enantioselective synthesis of the spirocyclic system of vannusal A

1 reference

12 December 2020

Actinopyrones A, B and C, new physiologically active substances. II. Physico-chemical properties and chemical structures

1 reference

12 December 2020

A convergent synthesis of the tricyclic architecture of the guanacastepenes featuring a selective ring fragmentation

1 reference

12 December 2020

Synthesis and reactions of the pestalotiopsin skeleton

1 reference

12 December 2020

Total synthesis of the marine natural product rac-dibromophakellstatin

1 reference

12 December 2020

Convergent, enantioselective syntheses of guanacastepenes A and E featuring a selective cyclobutane fragmentation

1 reference

12 December 2020

SmI2-induced umpolung of the C=N bond: first reductive conjugate addition of nitrones to alpha,beta-unsaturated esters

1 reference

12 December 2020

Total synthesis of the cyathane diterpenoid (+/-)-sarcodonin G

1 reference

12 December 2020

Asymmetric total syntheses of platensimycin

1 reference

12 December 2020

Samarium(II)-mediated reactions of gamma,delta-unsaturated ketones. Cyclization and fragmentation processes

1 reference

12 December 2020

Domino Reactions in Organic Synthesis

1 reference

12 December 2020

Biogenetic-type synthesis of the Calycanthaceous alkaloids

1 reference

12 December 2020

Preparation of useful synthetic intermediates of Taxol analogs, cyclooctenone derivatives

1 reference

12 December 2020

Switching between novel samarium(II)-mediated cyclizations by a simple change in alcohol cosolvent

1 reference

12 December 2020

Samarium(II)-mediated 4-exo-trig cyclization. A stereocontrolled approach to the core of pestalotiopsin A

1 reference

12 December 2020

Total synthesis of platensimycin

1 reference

12 December 2020

Toward the total synthesis of variecolin

1 reference

12 December 2020

Application of samarium diiodide (SmI2)-induced reduction of γ-acetoxy-α,β-enoates with α-specific kinetic electrophilic trapping for the synthesis of amino acid derivatives

1 reference

12 December 2020

Construction of the Complete Aromatic Core of Diazonamide A by a Novel Hetero Pinacol Macrocyclization Cascade Reaction We thank Drs. D. H. Huang and G. Suizdak for NMR spectroscopic and mass spectrometric assistance, respectively. Financial support

1 reference

12 December 2020

A mild and efficient synthesis of oxindoles: progress towards the synthesis of welwitindolinone A isonitrile

1 reference

12 December 2020

SmI(2)-promoted radical addition of nitrones to alpha,beta-unsaturated amides and esters: synthesis of gamma-amino acids via a nitrogen equivalent to the ketyl radical

1 reference

12 December 2020

Formal total synthesis of the potent renin inhibitor aliskiren: application of a SmI2-promoted acyl-like radical coupling

1 reference

12 December 2020

Expanding the scope of the acyl-type radical addition reactions promoted by SmI2

1 reference

12 December 2020

Coupling of Organic Halides with Carbonyl Compounds Promoted by SmI(2), the Kagan Reagent

1 reference

12 December 2020

Total synthesis of (+)-isoschizandrin utilizing a samarium(II) iodide-promoted 8-endo ketyl-olefin cyclization

1 reference

12 December 2020

Totalsynthese des marinen Naturstoffsrac-Dibromphakellstatin

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

The true structures of the vannusals, part 1: Initial forays into suspected structures and intelligence gathering

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

The true structures of the vannusals, part 2: Total synthesis and revised structure of vannusal B

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Some organic reactions promoted by samarium diiodide

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Divalent lanthanide derivatives in organic synthesis—II

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Twenty-five years of organic chemistry with diiodosamarium: an overview

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Application of lanthanide reagents in organic synthesis

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Indole-2,3-quinodimethanes: a new strategy for the synthesis of tetracyclic systems of indole alkaloids

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Divalent lanthanide derivatives in organic synthesis. 1. Mild preparation of samarium iodide and ytterbium iodide and their use as reducing or coupling agents

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Total Synthesis of Baccatin III and Taxol

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Enantioselective Total Synthesis of Taxol

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Enantioselective Total Synthesis of (−)-Taxol

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Lanthanides in organic synthesis. 2. Reduction of .alpha.-heterosubstituted ketones

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Recent developments in lanthanide mediated organic synthesis

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Recent Advancements in the Reformatsky Reaction

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

New Mechanistic Insights into Reductions of Halides and Radicals with Samarium(II) Iodide

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Improved Reactivity of Diiodosamarium by Catalysis with Transition Metal Salts

1 reference

https://api.crossref.org/works/10.1002%2FANIE.200902151

7 January 2021

Identifiers

DOI

10.1002/ANIE.200902151

1 reference

Consolidated OpenCitations Corpus – April 2017

OpenCitations bibliographic resource ID

2053309

OpenCitations bibliographic resource ID

2053309

1 reference