(11Z)-6-[4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy-14-ethyl-13-hydroxy-3,5,7,9,13-pentamethyl-1-oxacyclotetradec-11-ene-2,4,10-trione (Q105282397)

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group of stereoisomers with the chemical formula C₂₈H₄₇NO₈
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Language Label Description Also known as
English
(11Z)-6-[4-(dimethylamino)-3-hydroxy-6-methyloxan-2-yl]oxy-14-ethyl-13-hydroxy-3,5,7,9,13-pentamethyl-1-oxacyclotetradec-11-ene-2,4,10-trione
group of stereoisomers with the chemical formula C₂₈H₄₇NO₈

    Statements

    mass
    525.330167464 dalton
    1 reference
    based on heuristic
    inferred from SMILES
    chemical formula
    C₂₈H₄₇NO₈
    0 references
    canonical SMILES
    O=C1OC(CC)C(O)(C=CC(=O)C(C)CC(C)C(OC2OC(C)CC(N(C)C)C2O)C(C(=O)C1C)C)C
    0 references
    isomeric SMILES
    CCC1OC(=O)C(C)C(=O)C(C)C(OC2OC(C)CC(N(C)C)C2O)C(C)CC(C)C(=O)/C=C\C1(C)O
    1 reference
    based on heuristic
    inferred from InChI
    found in taxon
    Streptomyces venezuelae
    16 references
    stated in
    Production of pikromycin using branched chain amino acid catabolism in Streptomyces venezuelae ATCC 15439
    stated in
    Bioconversion of 12-, 14-, and 16-membered ring aglycones to glycosylated macrolides in an engineered strain of Streptomyces venezuelae.
    stated in
    A gene cluster for macrolide antibiotic biosynthesis in Streptomyces venezuelae: architecture of metabolic diversity
    stated in
    The Streptomyces venezuelae pikAV gene contains a transcription unit essential for expression of enzymes involved in glycosylation of narbonolide and 10-deoxymethynolide
    stated in
    Complete Genome Sequence of Streptomyces venezuelae ATCC 15439, Producer of the Methymycin/Pikromycin Family of Macrolide Antibiotics, Using PacBio Technology.
    stated in
    Characterization of the macrolide P-450 hydroxylase from Streptomyces venezuelae which converts narbomycin to picromycin
    stated in
    Hydroxylation of macrolactones YC-17 and narbomycin is mediated by the pikC-encoded cytochrome P450 in Streptomyces venezuelae.
    stated in
    Macrolide biosynthesis: a single cytochrome P450, PicK, is responsible for the hydroxylations that generate methymycin, neomethymycin, and picromycin in Streptomyces venezuelae.
    stated in
    Heterologous expression of tylosin polyketide synthase and production of a hybrid bioactive macrolide in Streptomyces venezuelae
    stated in
    The structure of DesR fromStreptomyces venezuelae, a β-glucosidase involved in macrolide activation
    stated in
    Complete genome sequence of Streptomyces venezuelae ATCC 15439, a promising cell factory for production of secondary metabolites
    stated in
    Biosynthesis and combinatorial biosynthesis of pikromycin-related macrolides in Streptomyces venezuelae
    stated in
    The structural basis for substrate anchoring, active site selectivity, and product formation by P450 PikC from Streptomyces venezuelae
    stated in
    Enhanced heterologous production of desosaminyl macrolides and their hydroxylated derivatives by overexpression of the pikD regulatory gene in Streptomyces venezuelae
    stated in
    Engineering of plant-specific phenylpropanoids biosynthesis in Streptomyces venezuelae.
    stated in
    Growth and differentiation properties of pikromycin-producing Streptomyces venezuelae ATCC15439

    Identifiers

     
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